Fluoridated elastomers: effect on disclosed plaque

OBJECTIVE: To investigate the effect of fluoridated elastomers on the quantity of disclosed dental plaque surrounding an orthodontic bracket in vivo. DESIGN: A randomized, prospective, longitudinal clinical trial, employing a split mouth, crossover design. Setting: The Orthodontic Departments of Liverpool and Sheffield Dental Hospitals. Subjects and methods: The subjects were 30 individuals about to start fixed orthodontic treatment. The study consisted of two experimental periods of 6 weeks with a washout period between. Fluoridated elastomers were randomly assigned at the first visit to be placed around brackets on 12, 11, 33 or 22, 21, 43. Non-fluoridated elastomers were placed on the contra-lateral teeth. After 6 weeks (visit 2) the elastomers were removed, the teeth disclosed and a photograph taken. Non-fluoridated elastomers were placed on all brackets for one visit to allow for a washout period. At visit 3, fluoridated elastomers were placed on the contra-lateral teeth to visit 1. At visit 4, the procedures at visit 2 were repeated. The photographs were scanned, then the area and proportion of the buccal surface covered with disclosed plaque was measured using computerized image analysis. A mixed-effects ANOVA was carried out with the dependent variable being the area or percentage area of disclosed plaque. RESULTS: There was no evidence of a systematic error and substantial agreement for the repeat readings of the same images. The only significant independent variable for the area of disclosed plaque was the subject (p<0.001). The significant independent variables for the proportion of disclosed plaque were the subject (p<0.001) and the tooth type (p=0.002). The independent variable describing the use of fluoridated or non-fluoridated elastomers was not significant for either the area or the proportion of disclosed plaque. CONCLUSION: Fluoridated elastomers do not affect the quantity of disclosed plaque around an orthodontic bracket

Non-isothermal modelling of the all-vanadium redox flow battery

An non-isothermal model for the all-vanadium redox flow battery (RFB) is presented. The two-dimensional model is based on a comprehensive description of mass, charge, energy and momentum transport and conservation, and is combined with a global kinetic model for reactions involving vanadium species. Heat is generated as a result of activation losses, electrochemical reaction and ohmic resistance. Numerical simulations demonstrate the effects of changes in the operating temperature on performance. It is shown that variations in the electrolyte flow rate and the magnitude of the applied current substantially alter the charge/discharge characteristics, the temperature rise and the distribution of temperature. The influence of heat losses on the charge/discharge behaviour and temperature distribution is investigated. Conditions for localised heating and membrane degradation are discusse

Transient non-isothermal model of a polymer electrolyte fuel cell

In this paper we present a one-dimensional transient model for the membrane electrode assembly of a polymer-electrolyte fuel cell. In earlier work we established a framework to describe the water balance in a steady-state, non-isothermal cathode model that explicitly included an agglomerate catalyst layer component. This paper extends that work in several directions, explicitly incorporating components of the anode, including a micro-porous layer, and accounting for electronic potential variations, gas convection and time dependence. The inclusion of temperature effects, which are vital to the correct description of condensation and evaporation, is new to transient modelling. Several examples of the modelling results are given in the form of potentiostatic sweeps and compared to experimental results. Excellent qualitative agreement is demonstrated, particularly in regard to the phenomenon of hysteresis, a manifestation of the sensitive response of the system to the presence of water. Results pertaining to pore size, contact angle and the presence of a micro-porous layer are presented and future work is discussed

Gas-phase and heat-exchange effects on the ignition of high- and low-exothermicity porous solids subject to constant heating

This article investigates the ignition of low-exothermicity reactive porous solids exposed to a maintained source of heat (hotspot), without oxygen limitation. The gas flow within the solid, particularly in response to pressure gradients (Darcy’s law), is accounted for. Numerical experiments related to the ignition of low-exothermicity porous materials are presented. Gas and solid products of reaction are included. The first stage of the paper examines the (pseudo-homogeneous) assumption of a single temperature for both phases, amounting to an infinite rate of heat exchange between the two. Isolating the effect of gas production and flow in this manner, the effect of each on the ignition time is studied. In such cases, ignition is conveniently defined by the birth of a self-sustained combustion wave. It is found that gas production decreases the ignition time, compared to equivalent systems in which the gas-dynamic problem is effectively neglected. The reason for this is quite simple; the smaller heat capacity of the gas allows the overall temperature to attain a higher value in a similar time, and so speeds up the ignition process. Next, numerical results using a two-temperature (heterogeneous) model, allowing for local heat exchange between the phases, are presented. The pseudo-homogeneous results are recovered in the limit of infinite heat exchange. For a finite value of heat exchange, the ignition time is lower when compared to the single-temperature limit, decreasing as the rate of heat exchange decreases. However, the decrease is only mild, of the order of a few percent, indicating that the pseudo-homogeneous model is in fact a rather good approximation, at least for a constant heat-exchange rate. The relationships between the ignition time and a number of physico-chemical parameters of the system are also investigated

The effect of oxygen starvation on ignition phenomena in a reactive solid containing a hot-spot

In this paper, we explore the effect of oxygen supply on the conditions necessary to sustain a self-propagating front from a spherical source of heat embedded in a much larger volume of solid. The ignition characteristics for a spherical hot-spot are investigated, where the reaction is limited by oxygen, that is, reactant + oxygen ? product. It is found that over a wide range of realistic oxygen supply levels, constant heating of the solid by the hot-spot results in a self-propagating combustion front above a certain critical hot-spot power; this is clearly an important issue for industries in which hazard prevention is important. The ignition event leading to the formation of this combustion wave involves an extremely sensitive balance between the heat generated by the chemical reaction and the depletion of the reactant. As a result, for small hot-spot radii and infinite oxygen supply, not only is there a critical power above which a self-sustained combustion front is initiated there also exists a power beyond which no front is formed, before a second higher critical power is found. The plot of critical power against hot-spot radius thus takes on a Z-shape appearance. The corresponding shape for the oxygen-limited reaction is qualitatively the same when the ratio of solid thermal diffusion to oxygen mass diffusion (N) is small and we establish critical conditions for the initiation of a self-sustained combustion front in that case. As N gets larger, while still below unity, we show that the Z-shape flattens out. At still larger values of N, the supercritical behaviour becomes increasingly difficult to define and is supplanted by burning that depends more uniformly on power. In other words, the transition from slow burning to complete combustion seen at small values of N for some critical power disappears. Even higher values of N lead to less solid burning at fixed values of power

Diagnostic SWOT appraisal of the wicker handicraft entrepreneurship development in Kashmir, India

Critical analyses of the perceptions on SWOT (strengths, weaknesses, opportunities and threats) have become a fundamental element of multi-criteria decision making for developing wicker handicraft entrepreneurship. The study examined the effectiveness and prioritization of entrepreneur's perceptions towards SWOT categories and factors and provided insights for developing wicker handicraft entrepreneurship in Pulwama district of Kashmir. Data were collected through structured interviews and focus group discussions of 100 wicker handicraft entrepreneurs of 20 villages selected by multi-stage random sampling. Simple descriptive statistics were used for the data analysis. Results showed that the factors like income generation (19.30%) and employment generation (19.00%) were viewed as most important strengths while labour intensive and less remunerative livelihood (18.80%) and seasonal subsistence (18.70%) were identified as main weaknesses. Further, poverty alleviation (20.70%), preservation of traditional art craft (19.00%) and improvement in public-private relations (17.50%) were adjudged as strong opportunities whereas limited marketing facilities (20.70%), lack of co-operative societies (18.90%) and harassment by officials in withies collection (16.50%) were seen as chief threats. The challenges (weaknesses and threats) (50.40%) for wicker handicraft entrepreneurship outweighed the prospects (strengths and opportunities) (49.60%) while the internal factors (strengths and weaknesses) (54.80%) prevailed over the external factors (opportunities and threats) (54.20%). F statistics (p&lt;0.05) indicated significant differences between the internal factors (strengths and weaknesses) and external factors (opportunities and threats). The results projected the basis to the policymakers to prioritize and address the prominent challenges and reinforce the prospects for conceptualizing, formulating and implementing the strategies for strengthening the wicker handicraft entrepreneurship

High order effects in one step reaction sheet jump conditions for premixed flames

The differences need to be understood between the leading order jump conditions, often assumed at a flame sheet in combustion theory, and the actual effect of a one step chemical reaction governed by Arrhenius kinetics. These differences are higher order in terms of a large activation temperature analysis and can be estimated using an asymptotic approach. This paper derives one order of asymptotic correction to the leading order jump conditions that are normally used for describing premixed laminar combustion, providing additional contributions that are due to curvature, flow through the flame sheet and the temperature gradient into the burnt gas. As well as offering more accurate asymptotic results, these can be used to estimate the errors that are inherent in adopting only the leading order version and they can point towards major qualitative changes that can occur at finite activation temperatures in some cases. Applied to steady non-adiabatic flame balls it is found that the effect of a non-zero temperature gradient in the burnt gas provokes the most serious deficiency in the asymptotic approach.<br/